Charge transport properties of semiconducting natural rubber (Cis 1,4-polyisoprene)

Charge Transport in Two-Photon Semiconducting Structures for Solar Fuels.

Semiconducting heterostructures are emerging as promising light absorbers and offer effective electron-hole separation to drive solar chemistry. This technology relies on semiconductor composites or photoelectrodes that work in the presence of a redox mediator and that create cascade junctions to promote surface catalytic reactions. Rational tuning of their structures and compositions is crucia...

Properties of Vulcanized Polyisoprene Rubber Composites Filled with Opalized White Tuff and Precipitated Silica

Opalized white tuff (OWT) with 40 μm average particle size and 39.3 m(2)/g specific surface area has been introduced into polyisoprene rubber (NR). Their reinforcing effects were evaluated by comparisons with those from precipitated silica (PSi). The cure characteristic, apparent activation energy of cross-link (E(ac)) and reversion (E(ar)), and mechanical properties of a variety of composites ...

The Cyclization of Natural Rubber

The effects of solvent, temperature, time, weight percent of catalyst on the rate and mechanism of cyclization of natural rubber (NR) was studied in toluene and xylene solutions having tin tetra chloride catalyst (SnCl4). Iodometric titration show, with 8% SnCl4 (based on polymer weight) cyclization occurs, leaving 27.4% of the total unsaturation. Infrared spectra of c...

Transport properties of single-crystalline n-type semiconducting PbTe nanowires.

Single-crystalline PbTe nanowires were synthesized using the chemical vapor transport method. They consisted of rock-salt structure PbTe nanocrystals uniformly grown in the [100] direction. We fabricated field-effect transistors using a single PbTe nanowire, providing evidence for its intrinsic n-type semiconductor characteristics. The values of the carrier mobility and concentration were estim...

Antithrombin activity of a polyelectrolyte synthesized from cis-1,4-polyisoprene.